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Hydrocarbon pollution along Moroccan coasts and BPH activity in the mussel Perna perna ArchiMer
Azdi, M.; Moukrim, A.; Burgeot, Thierry; Budzinski, H.; Chiffoleau, Jean-francois; Kaaya, A.; Zekhnini, A.; Narbonne, J. F.; Guarrigues, Ph..
Specimens of the mussel Perna perna were collected along Moroccan coasts to determine the concentrations of polycyclic aromatic hydrocarbons ( PAHs) bioaccumulated in the tissues, and to measure benzo[ a] pyrene hydroxylase (BPH) activity. Chemical analysis of PAHs show that the Mediterranean (Nador, Martil, Tanger) and central Atlantic coasts ( from Rabat to Jorf Lihoudi) are those most contaminated ( 351 245 ng.g(-1) dry weight in Tanger). The mussel contaminants were of mixed origin for most of the locations with non negligible inputs of petrogenic origin in many of them. Baseline levels of PAHs were between 6 and 55 ng.g(-1) dry weight. BPH activity showed significant correlation (r(s) = 0.64, P < 0.05) with total PAH concentrations at the six most...
Tipo: Text Palavras-chave: Mussel; Perna perna; Moroccan coasts; Polycyclic aromatic hydrocarbons; Benzoapyrene hydroxylase; Baseline level.
Ano: 2006 URL: http://archimer.ifremer.fr/doc/00000/10995/12929.pdf
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Imposex and butyltin concentrations in snails from the lagoon of Bizerta (Northern Tunisia) ArchiMer
Lahbib, Youssef; Abidli, Sami; Chiffoleau, Jean-francois; Averty, Bernard; Trigui El Menif, Najoua.
Imposex and butyltin concentrations were assessed in Hexaplex trunculus, Conus mediterraneus, Cyclope neritea and Nassarius mutabilis from Menzel Jemil, and H. trunculus and Stramonita haemastoma from the Bizerta channel. All females of the five species exhibited the characteristic development of male sex organs (penis and/or vas deferens). In Menzel Jemil, H. trunculus and C. mediterraneus exhibit similar imposex levels and were most affected (VDS reading 3-4). The development of a bud penis or a vas deferens sequence behind the right ocular tentacle was reported in Cyclope neritea and N. mutabilis (VDS 1). The concentration of tributyltin (TBT) was similar for the four species. The monobutyltin (MBT) was only detected in C. mediterraneus while the...
Tipo: Text Palavras-chave: Bioindicators; Gastropods; Organotins; Southern Mediterranean.
Ano: 2010 URL: http://archimer.ifremer.fr/doc/00015/12638/9569.pdf
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Influence des rejets urbains sur la contamination de la rivière de Morlaix par les métaux ArchiMer
Boutier, Bernard; Chiffoleau, Jean-francois; Gonzalez, Jean-louis; Noel, Joelle.
Raw and processed outflow from the Morlaix city sewage treatment plant were monitored every fourth hour for a 24 hours period, and monthly for eight months. The urban Hg, Cd, Cu, Zn and Pb outflow was shown to be much less than the river-borne flux. Sediments from the catchment area and estuary show that the influence of the town on the metal concentrations is limited to the harbour basin. The metal concentations are essentially controlled by granulometry.
Tipo: Text Palavras-chave: Métaux; Sédiment; Rivière de Morlaix.
Ano: 1990 URL: http://archimer.ifremer.fr/doc/00167/27793/25986.pdf
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Influence of an aggregate extraction in remobilizing contaminants from sediments in surface waters of the Bay of Seine (France) ArchiMer
Menet-nedelec, Florence; Riou, Philippe; Chiffoleau, Jean-francois; Maheux, Frank; Pierre-duplessix, Olivier; Rabiller, Emilie; Simon, Benjamin.
In coastal areas where monitoring data show that fine sediments contain contaminants, remobilization of these materials during aggregate extractions, which create a turbidity plume, might influence water quality. The eastern bay of Seine (France) is under the influence of the Seine plume, one of the most contaminated rivers in Europe. This study aimed at investigating remobilization of metals and organics from sediments in surface water during and after an aggregate dredging, through their behavior between total and dissolved phases. In this study area located 20 kilometers off Le Havre, sediments where sampled to identify potential contaminants. Unfiltered and filtered (< 0,2 µm) surface seawater samples were collected at different stages of the...
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Ano: 2015 URL: http://archimer.ifremer.fr/doc/00310/42077/41380.pdf
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Insights from the spatial and temporal distributions of mercury species and isotopes in bivalves from the french coastline ArchiMer
Briant, Nicolas; Knoery, Joel; Chouvelon, Tiphaine; Brach-papa, Christophe; Chiffoleau, Jean-francois; Savoye, Nicolas; Sonke, Jeroen.
Mercury cycles between atmosphere, terrestrial and aquatic reservoirs through a complex combination of transport and transformation processes, until it is buried in oceanic or terrestrial sediments. Monomethylmercury is the main species bioaccumulated and bioampli ed in the food chain. Knowledge of the origin (continental, oceanicorlocalsediment)ofthisspeciesforthelittoralenvironnment can still be improved. This study focuses on ~200 samples of bivalves (mussels: Mytilus edulis and Mytilus galloprovincialis and oysters: Crassostrea gigas and Isognomon alatus) from ~80 stations along the French coast. The goals of this study were i) to describe Hg levels, speciation and isotopic composition in various bioindicator bivalves from the French coastline, and ii)...
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Ano: 2017 URL: http://archimer.ifremer.fr/doc/00394/50562/51254.pdf
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Interactions between Volatile Reduced Sulfur Compounds and Metals in the Seine Estuary (France) ArchiMer
Cozic, Amandine; Viollier, E; Chiffoleau, Jean-francois; Knoery, Joel; Rozuel, Emmanuelle.
Concentrations of volatile hydrogen sulfide (H2S), carbonyl sulfide (OCS), methane thiol (MeSH), dimethyl sulfide (DMS), and dimethyl disulfide (DMDS) in the Seine estuary (France) were investigated in spring 2005 using samples collected from the first meter beneath the surface. Levels of dissolved metals (Ag, Cd, Cu, Zn, Ni, Co, Pb), suspended particulate matter, and particular organic carbon were also assessed. Maximum concentrations were 0.80 nM for H2S, 0.64 nM for OCS, 3.06 nM for MeSH, 11.06 nM for DMS, and 1.18 nM for DMDS, and different features were observed for the five volatile reduced sulfur compounds (VRSCs). Experiments were conducted to determine silver-VRSC conditional stability constants. Major interactions were observed between H2S and...
Tipo: Text Palavras-chave: Conditional stability constant; Metal; Volatile reduced sulfur compounds; Seine estuary.
Ano: 2008 URL: http://archimer.ifremer.fr/doc/2008/publication-5019.pdf
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La contamination chimique marine à Banyuls - Résultats du Réseau d'Observation de la Contamination CHimique (ROCCH) ArchiMer
Chiffoleau, Jean-francois; Claisse, Didier; Rousselet, Mathilde.
Tipo: Text
Ano: 2014 URL: http://archimer.ifremer.fr/doc/00187/29840/28294.pdf
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La contamination chimique sur le littoral Loire-Bretagne. Résultats de 35 années de suivi du Réseau d’Observation de la Contamination Chimique ArchiMer
Chiffoleau, Jean-francois.
Le ROCCH (Réseau d’Observatoire de la Contamination CHimique) est un observatoire de la contamination chimique du milieu marin littoral mis en place par le ministère chargé de l’Environnement à la fin des années 70 et mis en œuvre par IFREMER. Son objectif est de décrire les distributions de contaminants chimiques sélectionnés sur les côtes de France métropolitaine et certaines régions ultra-marines, et de suivre leur évolution temporelle. La stratégie consiste à mesurer ces contaminants dans des matrices intégratrices, tissus d’organismes inféodés à ces régions ou sédiments de surface. Depuis la fin des années 80, le ROCCH fournit des données environnementales aux conventions des mers régionales (convention OSPAR pour la Manche et l’Atlantique, convention...
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Ano: 2017 URL: http://archimer.ifremer.fr/doc/00405/51617/52170.pdf
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La contamination de la Gironde par le cadmium : origine, extension, importance ArchiMer
Boutier, Bernard; Chiffoleau, Jean-francois; Jouanneau, Jean-marie; Latouche, Claude; Philipps, Isabelle.
In 1979, the French monitoring program RNO (Réseau National d'Observation de la qualité du milieu Marin) pointed out a dramatic cadmium contamination in the oysters from the Gironde estuary (up to 100 ug -1, dry weight). The wild oyster-beds upstream the estuary were shown to be the most contaminated. This result tends to point to the river as the source of the cadmium contamination. At the same rime, uncontaminated oysters from Arcachon were transplanted in the Gironde estuary (La Fosse, Dau). This ex periment confirmed the importance and proved the permanence of the contamination. Very high concentrations of dissolved cadmium (400 ng. 1-1) were measured in the estuarine mixing zone. This phenomenon can be explained by the desorption of cadmiumfrom...
Tipo: Text Palavras-chave: Cadmium; Désorption; Estuaire; Bilan géochimique; Contamination des huîtres; Cadmium; Desorption; Estuary; Geochemical budget; Oyster contamination.
Ano: 1989 URL: http://archimer.ifremer.fr/doc/00167/27820/26013.pdf
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La contamination par le cadmium en Gironde et son extension sur le plateau continental ArchiMer
Boutier, Bernard; Chiffoleau, Jean-francois.
La répartition du cadmium dans l'eau, le sédiment et la matière en suspension de la Gironde, du proche plateau cohtinental et de la baie de Marennes-Oléron a été étudiée lors de trois campagnes réalisées en conditions de débits moyens ou d'étiage de la Garonne et de la Dordogne. Des apports anormaux de cadmium particulaire par la Garonne ont été mis en évidence. Après désorption ou solubilisation, ils sont expulsés sous forme dissoute, formant un panache très net mais peu étendu en dehors duquel les concentrations en cadmium dissous sont conformes aux valeurs habituellement observées en milieu côtier. Les teneurs en cadmium dissous du bas estuaire expliquent les fortes concentrations relevées dans les huîtres de ce secteur. Le caractère récent de la...
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Ano: 1986 URL: http://archimer.ifremer.fr/doc/00105/21583/19163.pdf
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L'argent (Ag, nanoAg) comme contaminant émergeant dans l'Estuaire de la Gironde : évaluations scientifiques et gouvernance des risques ArchiMer
Salles, Denis; Roumezi, Alexis; Lanceleur, Laurent; Schaefer, Jorg; Petit, Jerome; Blanc, Gerard; Coynel, Alexandra; Chiffoleau, Jean-francois; Auger, Dominique.
This article presents the results of multidisciplinary research (geochemistry, sociology) into the increasing concentrations of silver (Ag and nanoAg) in the environment and their potential impact on aquatic environments. We investigate simultaneously the risk of contamination of these environments by silver and the process of the social and political construction of this risk by water managers, health authorities, agencies and committees responsible for expert evaluations, environmental associations, and potential users of silver or nano-silver. Four updated models of risk construction allow us to understand the logic of arguments mobilized at this stage of the emerging risk. This interdisciplinary cooperation opens up possibilities for dealing with some...
Tipo: Text Palavras-chave: Environment; Estuaries; Geochemistry; Interdisciplinary communication; Nanotechnology; Risk assessment; Risk management; Silver; Sociology; Water pollutants.
Ano: 2013 URL: http://archimer.ifremer.fr/doc/00156/26736/24939.pdf
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Le chrome en milieu marin ArchiMer
Chiffoleau, Jean-francois.
This document constitutes a synthesis of current knowledge on the chromium biogeochemical cycle. The natural and anthropogenic sources are evaluated, the fluxes between the various geochemical compartments are assessed, with special attention to the riverine and atmospheric inputs to the marine environment. Chromium levels in these compartments are described and show in several areas a very high contamination of marine organisms. Due to the important toxicity of this element, further investigations are absolutely required to better understand its behaviour in the marine environment.
Tipo: Text Palavras-chave: Economic analysis; Air water exchanges; Toxicity; Biogeochemical cycle; Marine environment; Pollution; Chromium.
Ano: 1994 URL: http://archimer.ifremer.fr/doc/1994/rapport-1430.pdf
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Lead and its isotopes in the sediment of three sites on the Lebanese coast: Identification of contamination sources and mobility ArchiMer
Abi Ghanem, Carine; Chiffoleau, Jean-francois; Bermond, A.; Nakhle, K.; Khalaf, G.; Borschneck, D.; Cossa, Daniel.
Lead concentrations and isotopic composition of sediment samples collected from three sites within the Lebanese coastal zones were measured: at Akkar, Dora and Selaata. Akkar is located far from any direct source of contamination, while Dora and Selaata receive urban and industrial wastes, respectively. Low Pb concentrations (6-16 mu g g(-1)) were detected in the Akkar sediments, and high concentrations of Pb (70-101 mu g g(-1)) were detected in the Dora sediments. Measuring stable isotope ratios of Pb makes it possible to identify the principal sources of Pb in the Akkar sediments as Pb emitted from gasoline combustion and Pb originating from natural sources. On the other hand, Pb stable isotopic ratios in Dora sediments indicate that they are more highly...
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Ano: 2009 URL: http://archimer.ifremer.fr/doc/2009/publication-7326.pdf
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Long-term records of cadmium and silver contamination in sediments and oysters from the Gironde fluvial-estuarine continuum - Evidence of changing silver sources ArchiMer
Lanceleur, Laurent; Schaefer, Joerg; Chiffoleau, Jean-francois; Blanc, Gerard; Auger, Dominique; Renault, Sophie; Baudrimont, Magalie; Audry, Stephane.
The Gironde fluvial estuarine system is impacted by historic metal pollution (e.g. Cd, Zn, Hg) and oysters (Crassostrea gigas) from the estuary mouth have shown extremely high Cd concentrations for decades. Based on recent work (Chiffoleau et al., 2005) revealing anomalously high Ag concentrations (up to 65 mg kg(-1); dry weight) in Gironde oysters, we compared long-term (similar to 1955-2001) records of Ag and Cd concentrations in reservoir sediment with the respective concentrations in oysters collected between 1979 and 2010 to identify the origin and historical trend of the recently discovered Ag anomaly. Sediment cores from two reservoirs upstream and downstream from the main metal pollution source provided information on (i) geochemical background...
Tipo: Text Palavras-chave: Silver; Cadmium; Estuary; Oyster; Biomonitoring.
Ano: 2011 URL: http://archimer.ifremer.fr/doc/00060/17109/15071.pdf
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Metal concentrations in sediment and Nereis diversicolor in two Moroccan lagoons: Khnifiss and Oualidia ArchiMer
Idardare, Zaina; Chiffoleau, Jean-francois; Moukrim, A; Alla, A; Auger, Dominique; Lefrere, L; Rozuel, Emmanuelle.
Metal concentrations were measured monthly during an annual cycle (December 2004 to January 2006) in the tissues of Nereis diversicolor ragworms and sediment from two Moroccan Atlantic coastal lagoons: Oualidia in the north, situated in a highly industrialised urban area and Khnifiss in the south, far from anthropogenic influences. Relatively high levels of Zn, Ag and Cd were found in the sediment of Oualidia lagoon, while Ni concentrations were shown to be high at Khnifiss. The significant metal levels at Oualidia are a result of industrial and urban discharges, coupled with discharges from adjacent phosphate ore processing plants. Trace metal concentrations in worms vary according to season; they are usually high in winter and spring, in relation to the...
Tipo: Text Palavras-chave: Morocco; Coastal lagoons; Sediments; Nereis diversicolor; Metals.
Ano: 2008 URL: http://archimer.ifremer.fr/doc/2008/publication-6127.pdf
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Mise au point d'un test microcrustacé marin ArchiMer
Marcaillou-le Baut, Claire; Le Dean, Loic; Chiffoleau, Jean-francois; Sanjuan, Jane.
Because of the low number of currently available toxicity tests for marine environment, the authors describe an experimental procedure using a marine copepod : Tigriopus brevicornis. This method can be used to quantify the 50 % inhibition of larval production or growth. The variability in controls larval production reaches about 9 %. The toxicity of two contaminants : tributyltin (TBTF) and cadmium chloride (CdCl2) was determined with this method and the 50 % decreases in larval production are respectively 1,4 µg/l (TBTF) and 61 µg/l (Cd++).
Tipo: Text Palavras-chave: Test; Toxicité; Copépode; Étain; Cadmium; Test; Toxicity; Copepod; Tin; Cadmium.
Ano: 1988 URL: http://archimer.ifremer.fr/doc/00139/25036/23145.pdf
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Modelling Pb and Cd dynamics in the Seine estuary ArchiMer
Thouvenin, Benedicte; Gonzalez, Jean-louis; Chiffoleau, Jean-francois; Boutier, Bernard; Le Hir, Pierre.
The Seine estuary (France) is currently one of the world's most contaminated estuaries, due in particular to its high cadmium and lead content. Proper understanding of contaminant transfer, transformation and retention mechanisms throughout the estuary and up to the adjacent marine zone require a range of studies involving data collections, experiments, and modeling tool. A multivariable transport model (SiAM-3D) was used to simulate dissolved and particulate transport and it is applied to several calculation grids; a speciation model (MOCO) was used to select key species and obtain a schematic system representation. The coupled model for Cd and Pb was compared with field measurements. The complementary character of various tools (model applied to annual...
Tipo: Text Palavras-chave: 3D modeling; Cd and Pb trace metals; Seine estuary.
Ano: 2007 URL: http://archimer.ifremer.fr/doc/2007/publication-3009.pdf
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Monitoring of Pb Contamination in Loire Estuary: Trends, Distribution and Isotopic composition ArchiMer
Brach-papa, Christophe; Chiffoleau, Jean-francois; Knoery, Joel; Chouvelon, Tiphaine; Auger, Dominique; Bretaudeau-sanjuan, Jane; Crochet, Sylvette; Rozuel, Emmanuelle; Thomas, Bastien; Vasileva, Emilia; Oriana, Anna Maria.
The Loire River is one of the largest river systems in Western Europe and a major source of continental inputs to the marine environment in the Bay of Biscay. Its catchment area drains agricultural and industrial zones and its estuary is increasingly urbanized. Even if the Loire River is not considered as a highly polluted system, studies have shown estuarine Pb contamination due to industrial inputs and combustion of leaded gasoline until the mid 1990’s. A retrospective study, based on the analysis (Pb levels and isotopic composition) of mussel samples collected by the French mussel watch program (RNO/ROCCH) has highlighted this contamination and its trend between 1985-2005 (Couture et al., 2010). This poster furthers the work initiated by Couture et al....
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Ano: 2014 URL: http://archimer.ifremer.fr/doc/00188/29958/28404.pdf
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Monitoring of pollutant biochemical effects on marine organisms of the french coasts ArchiMer
Galgani, Francois; Bocquene, Gilles; Truquet, Philippe; Burgeot, Thierry; Chiffoleau, Jean-francois; Claisse, Didier.
The establishment of a network to assess pollutant effects is a current concern of international bodies such as the North Sea Task Force, the International Council for the Exploration of the Sea and the Intergovernmental Oceanographic Commission. With respect to the French coasts, three major considerations have been defined : the choice of monitoring areas ; the determination of a target species according to different criteria such as wide distribution, limited migration and contact with pollutant-rich sediments; and the selection of suitable parameters. This paper concerns the strategy adopted for the French coast. Ethoxyresorufin-O-deethylase, a specific cytochrome P450-dependent monooxygenase, measured by a simple microplate assay, was selected as an...
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Ano: 1992 URL: http://archimer.ifremer.fr/doc/00100/21169/18787.pdf
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Monitoring of trace metal contamination in the Souss estuary (South Morocco) using the clams Cerastoderma edule and Scrobicularia plana ArchiMer
Anajjar, E; Chiffoleau, Jean-francois; Bergayou, H; Moukrim, A; Burgeot, Thierry; Cheggour, M.
Concentrations of seven metals (Cd, Cu, Cr, Pb, Ni, Zn, Hg) were monitored monthly during 2 years in two bivalves, Cerastoderma edule and Scrobicularia plana collected from the Souss estuary (South Morocco) before and after the commissioning of a sewage treatment plant in November 2002. According to trace metals, changes in concentrations were observed mainly in S. plana, characterised by a decrease of Cu, Hg and Pb when Cd was clearly increasing. Conversely, no clear changes were observed in C. edule during the same periods. This study suggests the use of S. plana in the monitoring of trace metal contamination of such coastal marine environments.
Tipo: Text Palavras-chave: Monitoring; Waste water; Bivalves; Metals; South estuary.
Ano: 2008 URL: http://archimer.ifremer.fr/doc/2008/publication-4515.pdf
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